Aryana p's Senior Project Blog
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Project Title: Fabricating Fresher Futures: Exploring New Methods of Carbon Capture and Filtration BASIS Advisor: Dr. Lydia Felice Internship Location: ASU Center for Negative Carbon Emissions Onsite Mentor: Ms. Taysa Telenar |
Project Abstract
With the current onset of forest fires in California, it is evident that solutions to slowing the rate of climate change needs to be addressed. Although well-known clean energy sources such as solar power, wind power, and geothermal power can benefit the environment, they are place, time, and weather dependent. Carbon capture can provide an alternative solution or supplement to clean energy efforts, by filtering carbon dioxide from the air that is polluted by fossil fuel usage. This study will investigate a new method of membrane fabrication for DAC, with the purpose of increasing the efficiency of carbon filtration. Specifically, this study will focus on the spin coating of quaternary ammonium(QAM) onto polydimethylsiloxane(PDMS) membranes. QAMs membranes are shown to have higher rates of efficiency, but are prone to tears, phase separation, and inconsistent membranes. Creating a layer of QAMs on top of the standard PDMS membrane can allow for both increased strength and efficiency. After the PDMS membrane is created by combining PDMS with chloroform, the base membrane is formed. Membranes are then coated evenly with QAMs solution under a spin coater with 60 drops of solution while rotating at approximately 5000 rpm. After the membrane undergoes an ion exchange in acetone, it is tested for its efficiency. Efficiency is tested by filtering a carbon dioxide and nitrogen mixture in both humid and dry conditions to simulate outside conditions, to ensure the spin coated membranes have the potential to create a future with less net carbon dioxide emissions.
Vacuum Tests
Vacuum Tests This week, I began vacuum testing and analysis of each membrane. I put both the bulk QAMS and the spin-coated membrane into the set up. As per usual, this process involves a 24 hr time. Every four hours, the concentration of the carbon dioxide increases. It goes from 400, 1000, 10000, 140000, and... Read More
Tensile Strength
This week I was able to answer the question: Are spin coated QAMS membranes stronger then only QAMS membranes? I did this by conducting a tensile strength test, which essentially stretches the membrane until it snaps as a way of measuring the durability of the membrane. Tensile strength tests are conducted by first cutting the... Read More
Abstract Questions
This week definitely started off slow. My on-site advisor is presenting her thesis this week, and had significantly less time to advise me in the lab. Considering this, I decided to write this week’s lab on my experience outside of the lab. Typically, I arrive in the lab in the morning. After a few... Read More
Introducing: The Vacuum!
I might have lied when I said last week's results were the final results. Here's why: Something that I might not mention enough for this engineering project is its commercial uses. Typically, these carbon capture is being performed on large scales through sorbent based technology. Sorbent based technology is essentially the use of large amounts... Read More
Final Results
All the results are in: I have finally tested all of the membranes. Before I get into the results, I'd like to recenter on what's so cool about the polymer I am experimenting with: QAMS. The QAMS polymer, aside from having amines that are favorable to carbon dioxide separation, they also have something called moisture... Read More
Spin Coated Contact Angle Was Contacted!
CONTACT ANGLE CON'T One of the immediate questions following last week's experiment was whether the values of contact angle for spin coated QAMS onto another PDMS membrane would be different than a pure QAMS membrane. In other words, would having a layer beneath the QAMS polymer change the surface properties, or surface energy, of the... Read More
A Lesson from Confucius
"A drop of water shall be returned with a burst of spring" - Confucius Upon completely unrelated research to my project, I stumbled across these wise words which gave me a new burst of energy and hope for the research I had performed this week. Coincidentally, this week I performed multiple tests on my membranes, and in... Read More
Membrane Fabrication
This week, I finally was able to start my work at the lab. To catch up on lost time, I spent three full days making membranes. The process of making membranes includes (1)measuring proportions of materials and chemicals, (2)mixing chemicals, (3)pouring the solution into a teflon dish, (4) letting the solution set overnight in an... Read More
Data Sets: Quality Over Quantity
As I was still traveling this week, I decided to develop a skill that is necessary for all data analysis projects: Microsoft excel. Like the development of the diagram last week, knowing how data is processed and analysed can give me greater insight into how this project will work when I am in that lab. ... Read More
Carbon Capture: Taking a Walk In the Wrong Direction
For the beginning of my lab experience, I have unexpectedly found myself skipping to the last steps of the scientific method. Because I am traveling, I originally planned to simply perform calculations to prepare myself for experimentation and the creation of Carbon Capture membranes. However, I discovered that your environment truly does influence your work.... Read More